Volcanoes are found in association with midocean ridge systems (see seafloor spreading) and along convergent plate boundaries, such as around the Pacific Ocean's "Ring of Fire" (see plate tectonics), the ring of plate boundaries associated with volcanic island arcs and ocean trenches surrounding the Pacific Ocean. Continental volcanoes are also associated with converging plate boundaries, such as the volcanoes of the Cascade Range along the W coast of the United States. Isolated volcanoes also form in the midocean area of the Pacific apparently unrelated to crustal plate boundaries. These sea mounts and volcanic island chains, such as the Hawaiian chain, may form from rising magma regions called hot spots.

Shapes of volcanoes include composite cones, or stratovolcanoes, with steep concave sides such as Mt. St. Helens in the W United States; shield cones have gentle slopes and can be relatively large such as the Hawaiian Islands; and cinder cones as Parícutin in Mexico, with steep slopes made of cinderlike materials. Explosive eruptions build up steep-sided cones, while the nonexplosive ones usually form broad, low lava cones. Cones range in height from a few feet to nearly 30,000 ft (9 km) above their base. Usually the cone has as its apex a cavity, or crater, which contains the mouth of the vent. Such craters are typically less than 1 mi (1.6 km) across, but larger craters, called calderas, ranging in diameter from 3 mi to—in a few instances—50 mi (5–80 km), are formed by particularly large eruptions (see crater).

More than 500 volcanoes are known to have erupted on the earth's surface since historic times, and many more have erupted on the ocean floor unobserved by humans. Fifty volcanoes have erupted in the United States, which ranks third, behind Indonesia and Japan, in the number of historically active volcanoes. Of the world's active volcanoes, more than half are found around the perimeter of the Pacific, about a third on midoceanic islands and in an arc along the south of the Indonesian islands, and about a tenth in the Mediterranean area, Africa, and Asia Minor.

Evidence of extraterrestrial volcanic activity also has been found. Space probes have detected the remnants of ancient eruptions on earth's moon, Mars (which has the largest volcano in the solar system, Olympus Mons, 340 mi/550 km across and 15 mi/24 km high), and Mercury; these probably originated billions of years ago, since these bodies are no longer capable of volcanic activity. Triton (a satellite of Neptune), Io (a satellite of Jupiter), and Venus are the only bodies in the solar system besides earth that are known to be volcanically active. The volcanic processes that occur in the outer portion of the solar system are very different from those in the inner part. Eruptions on earth, Venus, Mercury, and Mars are of rocky material and are driven by internal heat. Io's eruptions are probably sulfur or sulfur compounds driven by tidal interactions with Jupiter. Triton's eruptions are of very volatile compounds, such as methane or nitrogen, driven by seasonal heating from the sun.

Terrestrial volcanic eruptions may take one or more of four chief forms, or phases, known as Hawaiian, Strombolian, Vulcanian, and Peleean. In the Hawaiian phase there is a relatively quiet effusion of basaltic lava unaccompanied by explosions or the ejection of fragments; the eruptions of Mauna Loa on the island of Hawaii are typical. The Strombolian phase derives its name from the volcano Stromboli in the Lipari, or Aeolian, Islands, N of Sicily. It applies to continuous but mild discharges in which viscous lava is emitted in recurring explosions; the ejection of incandescent material produces luminous clouds. A more explosive volcanic eruption is the Vulcanian, where the magma (lava before emission) accumulates in the upper level of the vent but is blocked by a hardened plug of lava that forms between consecutive explosions. When the explosive gases have reached a critical pressure within the volcano, masses of solid and liquid rock erupt into the air and clouds of vapor form over the crater. The Peleean, derived from Mt. Pelée, is the most violent, emitting fine ash; hot, gas-charged fragments of lava; and superheated steam in an incandescent "cloud" that travels downhill at great speed. Eruptions are often accompanied by torrential rains caused by the condensation of steam. The erupted fragments vary in size, including minute particles of volcanic dust and ash, lapilli (cinders or pellets), bombs (rounded or ellipsoidal masses of hardened magma), and huge masses called blocks.

Notable eruptions within historic times have been those of Vesuvius, in Italy (A.D. 79, 1906, and other times); Tambora, in Indonesia, where between 30 and 50 cu mi (125–210 cu km) of molten and shattered rock were blown into the air (1815); Krakatoa, near Java, material from which was sent 17 mi (27 km) into the atmosphere (1883); Parícutin, in Mexico, the volcano that began in a cornfield (1943); Hibok Hibok, on Camiguin island in the Philippines, which killed 84 people (1948); Besymianny, in Kamchatka, where 2 cu mi (8 cu km) of material were hurled into the air (1956); the peak of Tristan da Cunha, whose eruption caused the entire settlement to be evacuated (1961); Agung, in Bali, which killed 1,100 people (1963); Mt. St. Helens in Washington, which exploded with an energy equivalent to 10 million tons of TNT, killing 35, with 25 missing (1980); El Chichon in Mexico, which expelled about 500 million tons of ash and gas (1982); and Mt. Pinatubo in the Philippines, which killed over 500 people and ejected over 2 cu mi (8 cu km) of material (1991). Other notable volcanoes are Cotopaxi and Chimborazo (Ecuador), Iztaccihuatl and Popocatépetl (Mexico), Lassen Peak and Katmai (United States), and Etna (Sicily). Mauna Loa (Hawaii) is the world's largest active volcano, projecting 13,677 ft (4,170 m) above sea level and over 29,000 ft (8,850 m) above the ocean floor; from its base below sea level to its summit, Mauna Loa is taller than Mt. Everest. In 1963 the birth of the volcanic island Surtsey near Iceland was observed. In November of that year events began with a submarine eruption along the Mid-Atlantic Ridge. Eruption followed eruption until June, 1967, by which time the island stood 492 ft (150 m) above sea level and covered an area of almost 2 sq mi (3 sq km). The island has not grown since the last eruption, and it is presently volcanically quiet.

See S. Van Rose and I. Mercer, Volcanoes (2d ed., 1991); F. Martin, Volcano (1996); H. Sigurdsson, Melting the Earth: The History of Ideas on Volcanic Eruptions (1999); H. Sigurdsson et al., ed., Encyclopedia of Volcanoes (1999).